Use este identificador para citar ou linkar para este item: https://repositorio.ufms.br/handle/123456789/5313
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dc.creatorSingh, Sanjay Kumar-
dc.creatorGupta, Hari D.-
dc.creatorKhan, Mohammad U.-
dc.creatorBaghel, Santosh S.-
dc.date.accessioned2022-10-26T13:13:11Z-
dc.date.available2022-10-26T13:13:11Z-
dc.date.issued2010-11-15-
dc.identifier.issn1984-6428pt_BR
dc.identifier.urihttps://repositorio.ufms.br/handle/123456789/5313-
dc.description.abstractKinetic study of N-chlorosaccharin (NCSA) oxidation of malic acid (MA) in aqueous acetic acid medium in presence of perchloric acid has been investigated. The reactions exhibit first-order dependency in oxidant and HClO4 while order varies from one to zero in substrate. The reactions are acid catalyzed and retarded by the addition of saccharin, a byproduct of reaction. The rate of oxidation decreases with decrease in dielectric constant of the medium. The effect of temperature on the reaction has been investigated in the temperature range 313-333 K. The stochiometric studies revealed 1:1 mole ratio. Various thermodynamic parameters have been computed and a possible operative mechanism is proposed.pt_BR
dc.languageengpt_BR
dc.publisherFundação Universidade Federal de Mato Grosso do Sulpt_BR
dc.relation.ispartofOrbital: The Electronic Journal of Chemistrypt_BR
dc.rightsAcesso Abertopt_BR
dc.rightsAttribution-NonCommercial-NoDerivs 3.0 Brazil*
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/3.0/br/*
dc.subjectCinéticapt_BR
dc.subjectMalicum Acidumpt_BR
dc.subjectOxidaçãopt_BR
dc.subjectHidroxiácidospt_BR
dc.subjectFenômenos Bioquímicospt_BR
dc.subjectMedicamento Homeopáticopt_BR
dc.subjectÁcidos Carboxílicospt_BR
dc.subjectHydroxy Acidspt_BR
dc.subjectKineticspt_BR
dc.subjectOxidationpt_BR
dc.subjectBiochemical Phenomenapt_BR
dc.subjectHomeopathic Remedypt_BR
dc.subjectCarboxylic Acidspt_BR
dc.titleKinetics and mechanism of N-chlorosaccharin oxidation of malic acidpt_BR
dc.typeArtigo de Periódicopt_BR
dc.citation.volume2pt_BR
dc.citation.issue2pt_BR
dc.citation.spage118pt_BR
dc.citation.epage126pt_BR
dc.publisher.countryBrasilpt_BR
dc.publisher.initialsUFMSpt_BR
dc.subject.cnpqCNPQ::CIENCIAS EXATAS E DA TERRA::QUIMICApt_BR
Aparece nas coleções:Orbital: The Electronic Journal of Chemistry

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